Why does direct titration of aspirin with NaOH have a side reaction and how to prevent it?

Answers

Answer 1

Direct titration of aspirin with NaOH have a side reaction simply because aspirin is a weak acid

What is direct titration?

Direct titration can simply be defined as a type of titration in which a titrant of known concentration and volume is added to a substance in order to analyze it.

As the name implies, it is called direct titration simply because the one approaches the endpoint of the experiment directly.

Furthermore, the significance of direct titration is that it is used to find the quantity of a substance within a solution with chemical reactions.

So therefore, direct titration of aspirin with NaOH have a side reaction simply because aspirin is a weak acid

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Related Questions

State whether the following liquids are miscible with water (H2O) by entering "yes" or "no".

1) Benzene, C6H6


2) Methanol, CH3OH


3) Chloroform, CHCl3

Answers

1) yes, it is
2) no, it’s not
3) yes, it is

Which of the following properties allows water molecules to stick to othe types of molecules?

A) Viscosity
B) Adhesion
C) Surface Tension
D) Density

Answers

Answer:

B.) Adhesion

Explanation:

A.) is incorrect. Viscosity is a measure of internal friction that affects the fluidity of a liquid.

B.) is correct. Adhesion is the ability of water to stick to other substances (which are not water).

C.) is incorrect. Surface tension is the tension created by the bonds of the surface particles.

D.) is incorrect. Density is a ratio that compares mass to volume.

help! awarding 20 points ​

Answers

a. The circulatory system in fish is one-directional while it is two-directional in humans.

b. P has a high concentration of carbon dioxide and low oxygen concentration whereas Q has high oxygen concentration and low carbon dioxide concentration.

What is the circulatory system?

The circulatory system is the system of organism and tissues which help to transport blood and other fluids through the body of a living organism.

The organs of the circulatory system include:

The heartThe blood vessels - veins, arteries, capillaries

a. In the given diagram sowing the circulatory system of man and the fish, it can be seen that the direction of blood flow in the fish is one way through the heart. However, in humans, the direction of blood flow is two-way through the heart.

b. The gas in P has a high concentration of carbon dioxide and low oxygen concentration. However, the gas flowing through Q has high oxygen concentration and low carbon dioxide concentration.

In conclusion, the circulatory system is important in the exchange of gases in the body.

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Given the reaction

2 HI(g) <--> H2(g) + I2(g)

At 430 degrees Celsius, the equilibrium concentrations are [HI] = .5M, [H2] = 0.5 M, and [I2] = 1.5 M. What is the equilibrium constant (K)?







Group of answer choices

A. K = 3

B. K = 1.5

C. K = 0.33

D. K = 0.67

Answers

From the calculation, the equilibrium constant is obtained as 3. Option A

What is the equilibrium constant?

The term equilibrium constant shows the extent to which we could see the conversion of the reactants to products in a reaction system. Now we know that the equilibrium constant can be obtained by the use of the formula;

K = [H2] [I2]/[HI]^2

Now we have that at equilibrium;

[H2]  = 0.5 M

[I2] = 1.5 M

[HI] = 0.5M

It then follows that;

K = 1.5 * 0.5/( 0.5)^2

K = 3

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In order to dilute 40.0 mL of 0.600 M HCl to 0.200 M, the volume of water that would need to be added would be 200 mL. 80.0 mL. O 160 mL. 120 mL. 100 mL.​

Answers

Answer:

80 ml

Explanation:

Moles to start =  .04 L * .6 M/L = .024 moles

   this is how much must be in the final dilution

         .2 moles / liter * x liter  = .024 moles

                x = .024 / .2 = .12   liter final volume

           start with   . 040    then add .080   to get .12 liter

  .080 liter = 80 ml

Ideal Gas Law: Tutorial. At a party, you use a gas canister to fill balloons. The canister holds 4.47 moles of air. If the room is at 26.0°C and the gas pressure is 855 kilopascals, what is the volume of the canister? The volume of the canister is ___ liters. Type the correct answer in the box. Express your answer to the correct number of significant figures. Use the gas laws Fact sheet to help you.​

Answers

Answer:

13.0 L

Explanation:

To find the volume, you need to use the Ideal Gas Law:

PV = nRT

In this equation,

-----> P = pressure (kPa)

-----> V = volume (L)

-----> n = moles

-----> R = Ideal Gas constant (8.314 kPa*L/mol*K)

-----> T = temperature (K)

After converting the temperature from Celsius to Kelvin, you can plug the given values into the equation and simplify to find "V". The final answer should have 3 sig figs to match the sig figs of the given values.

P = 855 kPa                                  R = 8.314 kPa*L/mol*K

V = ? L                                           T = 26.0 °C + 273.15 = 299.15 K

n = 4.47 moles

PV = nRT

(855 kPa)V = (4.47 moles)(8.314 kPa*L/mol*K)(299.15 K)

(855 kPa)V = 11117.48496

V =  13.0 L

How many atoms in 56.4 g of platinum (Pt)

Answers

56.4 g of platinum will contain 1.7417 x  [tex]10^{23}[/tex] atoms

Number of atoms in substances

According to Avogadro, 1 mole of any substance contains 6.022 x [tex]10^{23}[/tex] atoms of the substance.

The problem is we don't know how many moles of platinum that are present in 56.4 g. Thus, the first thing is to calculate the number of moles of platinum present in 56.4 g of the substance.

This can be achieved by using the formula, mole = mass/molar mass. Keep in mind that the molar weight of platinum is 195 g/mol.

Therefore,

Mole of 56.4 g of platinum = 56.4/195 = 0.2892 moles

If,

1 mole of any substance = 6.022 x [tex]10^{23}[/tex] atoms

Then,

0.2892 moles of platinum = 0.2892 x 6.022 x [tex]10^{23}[/tex] atoms = 1.7417 x  [tex]10^{23}[/tex] atoms

In other words, 56.4 g of platinum will contain 1.7417 x  [tex]10^{23}[/tex] atoms 1.7417 x  [tex]10^{23}[/tex] atoms of the metal.

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How many moles of Hydrogen gas will be produced if you start with 2.5 moles of Magnesium and an excess of Hydrochloric Acid given the following balanced chemical reaction:

Mg + 2HCl → MgCl2 + H2

Group of answer choices

A. 1.25 moles

B. 5.0 Moles

C. 7.5 moles

D. 2.5 moles

Answers

Answer:

D.) 2.5 moles

Explanation:

To find the moles of H₂, you need to multiply the given value by the mole-to-mole ratio. This ratio consists of the coefficients in front of the relevant molecules. It is important to arrange the ratio in a way that allows for the cancellation of units.

1 Mg + 2 HCl -----> MgCl₂ + 1 H₂
^                                            ^

2.5 moles Mg            1 moles H₂
-----------------------  x  ---------------------  =  2.5 moles H₂
                                   1 mole Mg

environmental conditions of the ocean

Answers

The environmental conditions of the ocean are:

Light availabilityOxygen levelsWater movementSalinityDensity and pH.

What are the environmental impacts on the ocean?

In our oceans, there are known to be a lot of environmental conditions that are known to often affect the growth, survival and also the productivity of marine organisms. These are the ones listed above.

Note that the increased concentration of chemicals, e.g.  nitrogen and phosphorus is one that can be harmful to marine life.

Hence, The environmental conditions of the ocean are:

Light availabilityOxygen levelsWater movementSalinityDensity and pH.

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Draw clearly the structural formulas of the given compounds. (a) 3-methyl heptane​

Answers

See the attached image.

Is HF the most polar among covalent bonds?

Answers

Answer:

No.

Explanation:

HI is more polar than HF

25.0 mL of an LiOH solution were titrated with 29.15 mLof a 0.205 M H3PO4 solution to reach the equivalence point. What is the molarity of the LiOH solution?

Answers

Answer:

0.717 M LiOH

Explanation:

(Step 1)

Calculate the moles of HPO₄ using the molarity equation.

29.15 mL / 1,000 = 0.02915 L

Molarity = moles / volume (L)

0.205 M = moles / 0.02915 L

0.00598 = moles

(Step 2)

Convert moles HPO₄ to moles LiOH using the mole-to-mole ratio from reaction coefficients.

1 H₃PO₄ + 3 LiOH -----> Li₃PO₄ + 3 H₂O
^                ^

0.00598 moles H₃PO₄            3 moles LiOH
------------------------------------  x  --------------------------  =  0.0179 moles LiOH
                                                  1 mole H₃PO₄

(Step 3)

Calculate the molarity of LiOH using the molarity equation.

25.0 mL / 1,000 = 0.0250 L

Molarity = moles / volume (L)

Molarity = 0.0179 moles / 0.0250 L

Molarity = 0.717 M

When aqueous magnesium chloride reacts with liquid bromine

Answers

word equation: magnesium chloride + bromine -> magnesium bromide + chlorine
balance equation: MgCl2 + 2Br -> MgBr2 + 2Cl

Classify H3PO4 as a strong acid or a weak acid.​

Answers

Answer:

H3PO4 (phosphoric acid) is weak acid

Explanation:

This is because weak acid is an acid that ionizes only slightly in an aqueous solution.

A sample of nitrogen gas has a volume of 3.0 L at 25 degrees Celsius and 720 torr. What would the volume be at STP? (Hint: This is a combined gas law question).

Answers

Answer:

2.60 L

Explanation:

To find the new volume, you need to use the Combined Gas Law:

[tex]\frac{P_1V_1}{T_1}=\frac{P_2V_2}{T_2}[/tex]

In this equation, "P₁", "V₁", and "T₁" represent the initial pressure, volume, and temperature. "P₂", "V₂", and "T₂" represent the final pressure. volume, and temperature.

At STP, the pressure is 1.0 atm and the temperature is 273 K. Before you can plug the values into the equation, you need to convert pressure from torr to atm and the temperature from Celsius to Kelvin.

P₁ = 720 torr / 760 = 0.947 atm            P₂ = 1.0 atm

V₁ = 3.0 L                                                V₂ = ? L

T₁ = 25 °C + 273 = 298 K                       T₂ = 273 K

[tex]\frac{P_1V_1}{T_1}=\frac{P_2V_2}{T_2}[/tex]                                                  <----- Combined Gas Law

[tex]\frac{(0.947atm)(3.0L)}{298K}=\frac{(1.0atm)V_2}{273K}[/tex]                           <----- Insert values

[tex]\frac{2.84}{298K}=\frac{(1.0atm)V_2}{273K}[/tex]                                          <----- Multiply 0.947 and 3.0

[tex]0.00954=\frac{(1.0atm)V_2}{273K}[/tex]                                      <----- Simplify left side

[tex]2.60={(1.0atm)V_2}[/tex]                                         <----- Multiply both sides by 273

[tex]2.60L=V_2[/tex]                                                    <----- Divide both sides by 1.0

A student who prefers to study by converting lecture or written information into pictures, graphs, or charts, and then back into words
again: repeating the process as needed and watching videos most likely prefers which learning style?
O a. Visual
O b. Auditory
O c. Reading Writing
O d. Kinesthetic

Answers

The answer is C which is Reading Writing

A student who prefers to study by converting lecture or written information. The learning style of the student is reading writing. Thus option c is correct.

What is learning style?

Learning style is defined as the hypothesis that learners can be classified based on how they process information.

It can also be defined as a set of theories aimed at explaining variances in individual learning.

There are basically seven types of learning style.

Visual learning style Kinesthetic learning styleAural learning styleSocial learning styleSolitary learning styleVerbal learning styleLogical learning style

Reading and writing is one of the best style of learning as by this we can memorize the things for very long time.

Thus, the learning style of the student is reading writing. Thus option c is correct.

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Using standard heats of formation, calculate the standard enthalpy change for the following reaction.

2BrF3(g) -----> Br2(g) + 3F2(g)

Answers

Using standard heats of formation, the standard enthalpy change for the reaction  is  mathematically given as

= 542.11 kJ

What is the standard enthalpy change for the following reaction?

Generally, the equation for  standard enthalpy change is  mathematically given as

[tex]\Delta H rxn = \Delta H product - \Delta H reactant[/tex]

therefore,

[tex]\Delta H rxn = (\Delta H Br_2 + \Delta H 3F_2) - (\Delta H 2BrF_3)[/tex]

= (30.91 kJ + 3*0 kJ) - (2*(-255.6) kJ)

= 542.11 kJ

In conclusion, the standard enthalpy change for the following reaction is

= 542.11 kJ

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How many grams of water will be produced if you start with 4.0 grams of hydrogen and an excess of oxygen given the following balanced chemical equation?

2H2 + O2 → 2H2O

Group of answer choices

A. 32.0 grams

B. 36.0 grams

C. 54.0 grams

D. 18.0 grams

Answers

Answer:

B.) 36.0 grams

Explanation:

To find the mass of water, you need to (1) convert grams H₂ to moles (using the molar mass), then (2) convert moles H₂ to moles H₂O (using mole-to-mole ratio from reaction coefficients), and then (3) convert moles H₂O to grams (using the molar mass). It is important to arrange the conversions in a way that allows for the cancellation of units.

Molar Mass (H₂): 2(1.008 g/mol)

Molar Mass (H₂): 2.016 g/mol

Molar Mass (H₂O): 2(1.008 g/mol) + 15.998 g/mol

Molar Mass (H₂O): 18.014 g/mol

2 H₂ + O₂ -----> 2 H₂O
^                        ^

4.0 g H₂            1 mole             2 moles H₂O           18.014 g
---------------  x  ----------------  x  ------------------------  x  ---------------  = 36 g H₂O
                          2.016 g             2 moles H₂              1 mole

What if there was an inverse relationship between the temperature and the volume? How do you think the world might be different? How would this change our day-to-day lives?

Answers

If there was an inverse relationship between the temperature and the volume, our daily lives change because in high temperature things will contract.

What if there was an inverse relationship between the temperature and the volume?

If there was an inverse relationship between the temperature and the volume then with increasing temperature decrease occur in the volume of a substance. If this type of relationship is present in the world, the objects will contract when the temperature is high and expand when the temperature is low which make the solid materials expand at winter and contract at summer season.

So we can conclude that if there was an inverse relationship between the temperature and the volume, our daily lives change because in high temperature things will contract.

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will BeCO3 Hydrolyze in aqueous medium?. If so how?... very urgent..​

Answers

Answer:

BeCO3 will hydrolyze in an aqueous medium, yielding a basic solution.

Explanation:

In accord with the rules of salt hydrolysis, the cation [tex]Be^{2+}[/tex] can hydrolyze. The anion [tex]CO_{3} ^{2-}[/tex] can also hydrolyze, given that the resulting conjugate acid is weak.

Given that both ions hydrolyze, the Ka (acid ionization constant) and Kb (Base ionization constant) of each reactant (or product [that is, the conjugate acid and base for each ion]) must be compared.

Using the web (hopefully some sort of reference table has been provided to you):

Ka (for Be^2+) = [tex]3 * 10^{-7}[/tex]

Kb (for CO3^2-) = [tex]\frac{Kw (water)}{Ka (HCO3)}[/tex]

= [tex]\frac{1*10^{-14}}{4.7*10^{-11}}[/tex]

= [tex]2.1 * 10^{-4}[/tex]

The Kb > Ka, so the solution will be basic.

Hope this helps! My apologies if this answer is incorrect, I have not done this type of problem in a while.

How much heat is released if a 10.0 gram piece of aluminum is cooled from 70°C to 50°C?
Group of answer choices

A. +180 J

B. -200 J

C. -180 J

D. +200 J

Answers

C. The heat released when the aluminum is cooled from 70°C to 50°C is -180 J.

What is Specific heat capacity?

Specific heat capacity is the quantity of heat needed to raise the temperature per unit mass.

Heat released when the aluminum is cooled

The heat released when the aluminum is cooled from 70°C to 50°C is calculated as follows;

Q = mcΔθ

where;

m is mass of the aluminum c is specific heat capacityΔθ is change in temperature

Q = (10)(0.9)(50 - 70)

Q = -180 J

Thus, the heat released when the aluminum is cooled from 70°C to 50°C is -180 J.

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100.0 mL of a 0.695 M solution of KBr is diluted to 500.0 mL. What is the new concentration of the solution?

Answers

Answer:

0.116 M

Explanation:

(Step 1)

Calculate the amount of moles using the molarity ratio.

100.0 mL / 1,000 = 0.1000 L

Molarity = moles / volume

0.695 M = moles / 0.1000 L

0.0695 = moles

(Step 2)

Calculate the new molarity using the moles and new volume.

500.0 mL / 1,000 = 0.5000 L

Molarity = moles / volume

Molarity = 0.0695 moles / (0.1000 L + 0.5000 L)

Molarity = 0.0695 moles / (0.6000 L)

Molarity = 0.116 M

help me please with this question as soon as possible

Answers

0.5376 g is the minimum mass of sodium sulfite that we should add.

What is Molarity ?

Molarity (M) is defined as the number of moles of solute dissolved in 1L of solution. Molarity is also known as Molar concentration. The S.I unit of Molarity is molar (M) or mol/L.

The conversion sequence is

mL solution → L solution →  mol → g

[tex]80\ mL \times \frac{1\ L}{1000\ mL} \times \frac{0.04\ \text{mol Calcium nitrate solution}}{L} \times \frac{168\ \text{Calcium nitrate solution}}{\text{mol Calcium nitrate solution}}[/tex]

= 0.5376 g

Thus from the above conclusion we can say that 0.5376 g is the minimum mass of sodium sulfite that we should add.

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please solve this fast ​

Answers

Soft - Sponge
Metal - Iron
Transparent - Glass
Soluble - Salt
Opaque - Cardboard

A 24.5 mL sample of a 0.376 M aqueous hypochlorous acid solution is titrated with a 0.487 M aqueous potassium hydroxide solution. What is the pH at the start of the titration, before any potassium hydroxide has been added?

Answers

The pH of the solution when no base is added is 0.424.

An aqueous solution's acidity or basicity can be determined using the pH scale. The pH values of acidic solutions are typically lower than those of basic or alkaline solutions.

The chemical formula of hypochlorous acid is HClO.

1 mole of HClO produces 1 mole of hydrogen ions and 1 mole of fluoride ions.

KOH (aq) + HClO (aq) → KClO (l) + H2O (l)

To calculate the pH of the solution when no base is added, we use the equation:

[tex]p_{H} = - log {H}^{+}[/tex]

We are given:

[tex]H^{+} = 0.376 M[/tex]

Putting values in the above equation, we get:

[tex]p_{H} = - log (0.376)[/tex]

[tex]p_{H}[/tex] = 0.424

Hence, the pH of the solution when no base is added is 0.424

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Using the valence bond method, explain the structure of isocyanic acid in terms of the atomic bond method.

Answers

The structure of isocynide is

N=C

What is the importance of VSEPR theory?

Valence bond theory describes the electronic structure of molecule .The theory says that electrons fills the atomic orbitals of an atom within a molecule .

In the structure of isocynide there are triple bonds between Nitrogen and carbon . The bond length is 115.8pm and the bond angle is 180°. There is two pi and one sigma bond .

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The structure of isocynide is H--N=C

What is meant by valence bond?

Valence bond (VB) theory is a chemical bonding theory that describes the chemical bonding between two atoms. Like molecular orbital (MO) theory, it explains sticking using principles of quantum mechanics. According to valence bond theory, sticking is caused by the overlapping of half-filled atomic orbitals.

What is a valence bond structure?

Valence Bond theory represents covalent bond formation as well as the electronic form of molecules. The theory assumes that electrons inhabit atomic orbitals of individual atoms within a molecule, and that the electrons of one atom are drawn to the nucleus of another atom.

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What mass (g) of solute is contained in 417 mL of a 0.327 M magnesium fluoride (MgF2) solution?

Answers

Answer: [tex]\Large\boxed{m=8.5~g}[/tex]

Rounded to the nearest 2 significant figures

Explanation:

Given information

Volume of Solution = 417 mL

Molarity of Solution = 0.327 M (mol / L)

Given molecular weight

Mg (Magnesium) = 24 g / mol

F (Flourine) = 19 g / mol

Total Weight (MgF₂) = 24 + 2 × 19 = 62 g /mol

Given formula

m = V × M × n

m = massV = VolumeM = Molarityn = molar mass (molecular weight)

Convert the unit of volume to Liter

1 L = 1000 mL

417 mL = 417 / 1000 = 0.417 L

Substitute values into the given formula

m = (0.417) × (0.327) × (62)

Simplify by multiplication

m = 136.359 × 62

[tex]\Large\boxed{m=8.5~g}[/tex]

Hope this helps!! :)

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Find the number of moles of the following substances 210 grams of NaHCO3

Answers

The number of moles of 210 grams of NaHCO₃ is 2.5 moles.

How to find the Number of moles ?

To calculate the number of moles use the formula

Number of moles = [tex]\frac{\text{Given Mass}}{\text{Molar Mass}}[/tex]

Mass of NaHCO₃ = 210 g

Now we have to find the Molar mass of NaHCO₃

= Atomic mass of Na + Atomic mass of H + Atomic mass of C + 3 (Atomic mass of O)

= 23 + 1 + 12 + 3 (16)

= 36 + 48

= 84 g/mol

Now put the value in above formula we get

Number of moles = [tex]\frac{\text{Given Mass}}{\text{Molar Mass}}[/tex]

                             = [tex]\frac{210\ g}{84\ g/mol}[/tex]

                             = 2.5 moles

Thus from the above conclusion we can say that The number of moles of 210 grams of NaHCO₃ is 2.5 moles.

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Once balanced, what is the coefficient of HCl in the following reaction:

Mg + HCl → MgCl2 + H2

Group of answer choices

A. 1

B. 2

C. 0

D. 3

Answers

Once balanced, the coefficient of HCl in the following reaction: Mg + HCl → MgCl2 + H2 is 2 (option B).

How is a chemical reaction balanced?

A chemical reaction is said to be balanced when the number of moles of each atom of an element on both sides of the equation is the same.

According to this question, magnesium reacts with hydrochloric acid to form magnesium chloride and hydrogen gas as follows:

Mg + HCl → MgCl2 + H2

However, to balance the equation, we make use of coefficients, which are numbers placed in front of a compound to make the number of moles of atoms equal.

The balanced equation is as follows:

Mg + 2HCl → MgCl2 + H2

Therefore, once balanced, the coefficient of HCl in the following reaction: Mg + HCl → MgCl2 + H2 is 2.

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If an electron falls from the n = 2 to the n = 1 energy levels in a Hydrogen atom what wavelength of light is emitted?
Group of answer choices

A. 122 nm

B. 1024 nm

C. 97 nm

D. 103 nm

Answers

The wavelength is obtained as 122 nm. Option A

What is the wavelength?

We know that from the Bohr model of the atom, an electron can move from a higher energy level to a lower energy level or from a lower energy level to a higher energy level. This is the idea of energy quantization as put forward by Neill Bohr.

The wavelength can be obtained by the use of the formula;

1/λ = RH(1/n^2initial - 1/n^2 final)

λ = wavelength of the emitted light

RH = Rydberg's constant

n intial = initial energy level

nfinal = final energy level

Thus;

1/λ = 1.09 * 10^7(1/1^2 - 1/2^2)

1/λ = 1.09 * 10^7( 1 - 0.25)

λ = 122 nm

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Schools are required to provide students training in recognizing symptoms of catastrophic injuries, including head and neck injuries, concussions, asthma attacks, heatstroke, cardiac arrest and injuries requiring use of an aed, the risks of using nutritional supplements. True or false?. What effect did the immigration act of 1965 have on immigration from mexico? check all of the boxes that apply. I am so little when separated alone yet so big when more of me is combined. Kids love to play with me on a hot summer day near water. What am I? Drag each pair of coordinates to the correct location on the image. Match each pair of pilar coordinates to the equivalent polar coordinates on the image. ________ is used to describe the relationship between two things of the same type, such as one person being married to another person. Employers may pay nonexempt employees who work fluctuating schedules a fixed salary. in these cases, the extra pay is? Tanya is 12 years older than Leah. Three years ago, Tanya was five times as old as Leah.What is the age of Tanya and Leah now? What portion of the brain is served by the anterior and middle cerebral arteries? Find the total surface area. A. 78 B. 98 C. 69 D. 92 Your friends and you notice a classmate who always has brand new clothes, shoes, and electronics. What would you need to know in order to tell if this classmates family is actually wealthy? The law of Cosines Is...... Which ics functional area arranges for resources and needed services to support achievement. Instructions: Find the surface area of each figure. Round your answers to the nearest tenth, if necessary. John is 12 meters away from a cliff and looks up to the top of the cliff at an angle of 45. His eyes are 2 meters above the ground. How tall is the cliff? If two organisms were locked in an antagonistic coevolutionary relationship, which one would win? When the points in a scatter plot cluster closely around the regression line, the correlation can be said to be? What factors old and new, led to the widespread outbreak of revolutions in 1848? Determine whether the given correlation coefficient is statistically significant at the specified level of significance and sample size. r=0. 599, =0. 01, n=11 What are the major differences in Brutus and Antony's speeches? Organelles called lysosomes contain ______ that break down food particles, old organelles, and other cellular debris.